KINETICS OF EXCITED MOLECULES: I. KETENE
作者:
B. T. Connelly,
Gerald B. Porter,
期刊:
Canadian Journal of Chemistry
(NRC Available online 1958)
卷期:
Volume 36,
issue 12
页码: 1640-1648
ISSN:0008-4042
年代: 1958
DOI:10.1139/v58-238
出版商: NRC Research Press
数据来源: NRC
摘要:
The primary quantum yield of ketene decomposition was studied as a function of pressure, temperature, and wavelength. The results show that excited vibronic states are formed which may be degraded before dissociation can occur. The ratio of the rate of collisional degradation to the rate of dissociation decreases from 164 liters/mole at 3340 Å to 16.8 liters/mole at 3130 Å.
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