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Point Defect Trapping in Crystal Growth

 

作者: W. W. Webb,  

 

期刊: Journal of Applied Physics  (AIP Available online 1962)
卷期: Volume 33, issue 6  

页码: 1961-1971

 

ISSN:0021-8979

 

年代: 1962

 

DOI:10.1063/1.1728875

 

出版商: AIP

 

数据来源: AIP

 

摘要:

The possibility of trapping significant quantities of point defects during growth of a crystal is considered. Calculations are based on the well‐established theory of growth from the vapor on vicinal surfaces and the results are applied approximately to more complex cases. Concentrations of point defects, either above or below equilibrium, can be trapped under some conditions. In most cases the effect is insignificant. The crucial characteristic of a growth condition is defined by the dimensionless parameterDv/RdwhereDvis the bulk diffusion coefficient for point defects (vacancies),Ris the growth rate, anddis the ``effective thickness'' of the surface. The value ofdis about 1 atom layer in most cases, but may be greater at solid‐melt interfaces. Large supersaturations of point defects may be trapped ifDv/Rdis small. For very large values ofDv/Rd, subsaturation concentrations of vacancies may be trapped. Growth trapping accounts for the loss of dislocations from metal whisker crystals during growth and may support a simple explanation of some substructure formation during solidification of pure single crystals.

 

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