Analysis of Polynuclear Aromatic Hydrocarbons in Shale Oil and Diesel Particulates
作者:
YulinL. Tan,
期刊:
Analytical Letters
(Taylor Available online 1988)
卷期:
Volume 21,
issue 4
页码: 553-562
ISSN:0003-2719
年代: 1988
DOI:10.1080/00032718808081237
出版商: Taylor & Francis Group
关键词: Polynuclear aromatic hydrocarbons;Soxhlet extraction;ultrasonic extraction;Sephadex LH-20 gel filtration chromatography;silica gel absorption chromatography;gas chromatrography;Mass spectrometry
数据来源: Taylor
摘要:
We participated in the interlaboratory studies conducted by the National Bureau of Standards/Department of Energy (NBS/DOE) Analytical Characterization Group in which shale oil and diesel particulates were analyzed for three ring to six ring polynuclear aromatic hydrocarbons (PAH). Diesel particulates were extracted by Soxhlet or ultrasonic extraction. The PAH fraction was isolated with Sephadex LH-20 gel filtration chromatography and silica gel adsorption chromatography. The individual PAH was identified and quantitated with a gas chromatography/flame ionization detector and computerized gas chromatography/mass spectrometry. The combination of gel filtration and adsorption chromatography was found to be effective in isolating PAH from various complex sample matrices for further instrumental analysis. The results compared favorably with methods used among the other participating laboratories.
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