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Scaling laws for diamond chemical‐vapor deposition. I. Diamond surface chemistry

 

作者: D. G. Goodwin,  

 

期刊: Journal of Applied Physics  (AIP Available online 1993)
卷期: Volume 74, issue 11  

页码: 6888-6894

 

ISSN:0021-8979

 

年代: 1993

 

DOI:10.1063/1.355063

 

出版商: AIP

 

数据来源: AIP

 

摘要:

A simplified model of the gas‐surface chemistry occurring during chemical‐vapor deposition of diamond thin films is presented. The model results in simple scaling relations, useful for process scale‐up and optimization, for growth rate and defect density in terms of the local chemical environment at the substrate. A simple two‐parameter expression for growth rate is obtained, which with suitable parameter choices reproduces the results of more detailed mechanisms and experiment over two orders of magnitude in growth rate. The defect formation model suggests that the achievable growth rate at specified defect density scales approximately quadratically with the atomic hydrogen concentration at the substrate.  

 

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