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MINIEMULSION FORMATION BY TRANSITIONAL INVERSION

 

作者: Matilde MIÑANA-PEREZ,   Caroline GUTRON,   Carine ZUNDEL,   JoséM. ANDEREZ,   JeanL. SALAGER,  

 

期刊: Journal of Dispersion Science and Technology  (Taylor Available online 1999)
卷期: Volume 20, issue 3  

页码: 893-905

 

ISSN:0193-2691

 

年代: 1999

 

DOI:10.1080/01932699908943826

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

Very fine emulsions with droplet size in the sub-micron range, often called miniemulsions, are prepared by the moderate (magnetic) stirring of a system undergoing a dynamic transitional inversion driven by a continuous change in physicochemical formulation (here temperature). Near optimum formulation for three-phase systems, the ultralow interfacial tension favors the drop breaking rate, and fine emulsions can be made. However, this region is also known for its rapid coalescence rate. Thus, a high enough stability can be attained only by shifting the formulation away from optimum as soon as the emulsion is made. Moreover, a rapid change in formulation through the three-phase region also results in a separation phenomenon that can be harnessed to produce ultra fine droplets.

 

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