Ozonation of Aqueous Solutions of Nitrogen Heterocyclic Compounds : Benzotriazoles, Atrazine and Amitrole
作者:
B. Legube,
S. Guyon,
M. Doré,
期刊:
Ozone: Science & Engineering
(Taylor Available online 1987)
卷期:
Volume 9,
issue 3
页码: 233-246
ISSN:0191-9512
年代: 1987
DOI:10.1080/01919518708552338
出版商: Taylor & Francis Group
关键词: Ozone;Nitrogen Heterocyclic Compounds;Pesticides;Ozone Oxidation Products;Amitrole;Benzotriazoles;Atrazine
数据来源: Taylor
摘要:
Study of the ozonation of aqueous solutions of four heterocyclic nitrogen compounds, at slightly acidic pH in a heterogeneous gas-liquid system, showed that the reactivities of these compounds are different. Amitrole, a five-membered ring heterocycle, has been found to be a highly reactive compound, while atrazine, a six-membered ring heterocycle, has been found to be a poorly reactive compound. The benzotriazoles, benz-fused five-membered ring heterocycles, present intermediate reactivities. Moreovoer, the chemical natures of the ozonation by-products have been found to be different between amitrole and atrazine. With atrazine, ozone did not open the heterocyclic ring, and led to the formation of a trioxotriazine. With amitrole, ozone broke the heterocyclic ring and formed mainly formamide.
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