Laser Desorption Mass Spectra of Biomedical Polymers: Biomer and Avcothane
作者:
S.W. Graham,
D.M. Hercules,
期刊:
Spectroscopy Letters
(Taylor Available online 1982)
卷期:
Volume 15,
issue 1
页码: 1-19
ISSN:0038-7010
年代: 1982
DOI:10.1080/00387018208062643
出版商: Taylor & Francis Group
关键词: Laser desorption mass spectrometry;polymers;Avcothane;Biomer;polyether;polyurethane
数据来源: Taylor
摘要:
Biomer is a segmented polyether/polyurethane in which the monomer of the polyether is tetramethylene oxide and the urethane linkages are with toluene-2,4-diisocyanate. Both the positive- and negative-ion laser desorption mass spectra of Biomer show peaks corresponding to fragments from the polyether and the polyurethane. Avcothane is also a segmented polyether/polyurethane, however polydimethylsiloxane is blended into this polymer. The polyether of Avcothane is polypropylene glycol and the urethane bond is formed using toluene-2,4-diisocyanate. The positive and negative ion mass spectra of Avcothane contain peaks which have been assigned to polyether, polyurethane, and polydimethylsiloxane components.
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