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Laser Desorption Mass Spectra of Biomedical Polymers: Biomer and Avcothane

 

作者: S.W. Graham,   D.M. Hercules,  

 

期刊: Spectroscopy Letters  (Taylor Available online 1982)
卷期: Volume 15, issue 1  

页码: 1-19

 

ISSN:0038-7010

 

年代: 1982

 

DOI:10.1080/00387018208062643

 

出版商: Taylor & Francis Group

 

关键词: Laser desorption mass spectrometry;polymers;Avcothane;Biomer;polyether;polyurethane

 

数据来源: Taylor

 

摘要:

Biomer is a segmented polyether/polyurethane in which the monomer of the polyether is tetramethylene oxide and the urethane linkages are with toluene-2,4-diisocyanate. Both the positive- and negative-ion laser desorption mass spectra of Biomer show peaks corresponding to fragments from the polyether and the polyurethane. Avcothane is also a segmented polyether/polyurethane, however polydimethylsiloxane is blended into this polymer. The polyether of Avcothane is polypropylene glycol and the urethane bond is formed using toluene-2,4-diisocyanate. The positive and negative ion mass spectra of Avcothane contain peaks which have been assigned to polyether, polyurethane, and polydimethylsiloxane components.

 

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