首页   按字顺浏览 期刊浏览 卷期浏览 Synthese von Makrocyclen durch Ringerweiterung von 14gliedrigen cyclischen Imiden
Synthese von Makrocyclen durch Ringerweiterung von 14gliedrigen cyclischen Imiden

 

作者: Thomas Koch,   Vassil I. Ognyanov,   Manfred Hesse,  

 

期刊: Helvetica Chimica Acta  (WILEY Available online 1992)
卷期: Volume 75, issue 1  

页码: 62-68

 

ISSN:0018-019X

 

年代: 1992

 

DOI:10.1002/hlca.19920750104

 

出版商: WILEY‐VCH Verlag GmbH

 

数据来源: WILEY

 

摘要:

Synthesis of Macrocyles by Ring Enlargement of 14‐Membered Cyclic ImidesIn the presence of a base, cyclododecanone derivative2, activated in α‐position by an allyloxycarbonyl group, underwent ring enlargement with isocyanates to give 14‐membered imides (Schemes 1–3). Cleavage of the activating group gave new 14‐membered imides which could be transformed by further ring‐enlargement reactions into new macrocycl

 

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