Synthese von Makrocyclen durch Ringerweiterung von 14gliedrigen cyclischen Imiden
作者:
Thomas Koch,
Vassil I. Ognyanov,
Manfred Hesse,
期刊:
Helvetica Chimica Acta
(WILEY Available online 1992)
卷期:
Volume 75,
issue 1
页码: 62-68
ISSN:0018-019X
年代: 1992
DOI:10.1002/hlca.19920750104
出版商: WILEY‐VCH Verlag GmbH
数据来源: WILEY
摘要:
Synthesis of Macrocyles by Ring Enlargement of 14‐Membered Cyclic ImidesIn the presence of a base, cyclododecanone derivative2, activated in α‐position by an allyloxycarbonyl group, underwent ring enlargement with isocyanates to give 14‐membered imides (Schemes 1–3). Cleavage of the activating group gave new 14‐membered imides which could be transformed by further ring‐enlargement reactions into new macrocycl
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