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Angular resolved Raman scattering using fiber optic probes

 

作者: G. R. Trott,   T. E. Furtak,  

 

期刊: Review of Scientific Instruments  (AIP Available online 1980)
卷期: Volume 51, issue 11  

页码: 1493-1496

 

ISSN:0034-6748

 

年代: 1980

 

DOI:10.1063/1.1136110

 

出版商: AIP

 

数据来源: AIP

 

摘要:

A unique method for obtaining angular resolved Raman spectra is described, the purpose of which will be to study the angular dependence of the surface enhanced Raman effect from molecules adsorbed on metal substrates. Our design employs two flexible fiber optic bundle probes which are optically coupled to the laser and the monochromator respectively. The probes which define the incident and detected angular resolution at 20°, can be independently positioned in 45° azimuthal angle increments and at 0°, 22 1/2°, 45°, and 67 1/2° with respect to the sample surface normal. In a test of the performance of the system, the angular dependence of the Raman intensity from the 992 cm−1mode of benzene was recorded. The results are in excellent agreement with previous data, thus demonstrating the practicality of our device.

 

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