Aqueous Polymerization of Methyl Methacrylate. II
作者:
J.S. Shukla,
R.K. Ttwari,
期刊:
Journal of Macromolecular Science: Part A - Chemistry
(Taylor Available online 1982)
卷期:
Volume 18,
issue 5
页码: 759-771
ISSN:0022-233X
年代: 1982
DOI:10.1080/00222338208074433
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
Aqueous polymerization of methyl methacrylate (MMA) initiated by potassium persulfate-thioglycollic acid (TGA) redox system has been studied at 30°C under nitrogen atmosphere. The rate of polymerization is expressed byThe polymerization was studied over the temperature range 20–45°C. The activation energy calculated from an Arrhenius plot was found to be 8.34 kcal/mol (34.9 kJ/mol). The effects of inorganic electrolytes and organic solvents on polymerization were also investigated. Except for manganese sulfate and sodium oxalate, all of them depressed both the initial rate and the limiting conversion.
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