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The Dibutylphosphate + Benzene System

 

作者: H. Atrops,   Friedrich Kohler,   Alexander Apelblat,  

 

期刊: Berichte der Bunsengesellschaft für physikalische Chemie  （WILEY Available online 1983）
卷期: Volume 87, issue 1  

页码: 38-42

 

ISSN:0005-9021

 

年代: 1983

 

DOI:10.1002/bbpc.19830870111

 

出版商: Wiley‐VCH Verlag GmbH&Co. KGaA

 

关键词: Exzeßvolumina;Flüssige Mischungen;Gibbs'sche Exzeßenergien;Thermodynamik

 

数据来源: WILEY

 

摘要:

AbstractMelting curves and densities have been determined for this system, from which activity coefficients, excess Gibbs energies and excess volumes were evaluated. The results are interpreted similar to the acetic acid + benzene system, with dibutylphosphate (HDBP) to undergo strong dimerization. But with HDBP + benzene, it seems necessary to consider the size differences of the species.

 

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