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Synthesis ofC-Ring Hydroxylated Neoflavonoids by Ligand Coupling Reactions

 

作者: DervillaM.X. Donnelly,   Jean-Pierre Finet,   PatrickJ. Guiry,   MartinD. Rea,  

 

期刊: Synthetic Communications  (Taylor Available online 1999)
卷期: Volume 29, issue 15  

页码: 2719-2730

 

ISSN:0039-7911

 

年代: 1999

 

DOI:10.1080/00397919908086434

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

Reaction of 4-trifluoromethanesulfonyloxycoumarin derivatives with benzyloxyphenylboronic acid derivatives under modified Suzuki reaction conditions afforded the corresponding neoflavones. Selective debenzylation took place in high yields when the palladium-catalysed hydrogenolysis was performed in the presence of acetic acid.

 

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