Determination of Limits for a Linear Regression or Calibration Curve
作者:
SwallowWilliam H.,
TroutJ. Richard,
期刊:
Journal of Quality Technology
(Taylor Available online 1983)
卷期:
Volume 15,
issue 3
页码: 118-125
ISSN:0022-4065
年代: 1983
DOI:10.1080/00224065.1983.11978858
出版商: Taylor&Francis
关键词: Accuracy;Calibration;Heteroscedasticity;Linear Regression;Nonlinearity;Precision
数据来源: Taylor
摘要:
Trace analysis has become increasingly more important because of its connection with recent environmental, chemical, and biological concerns; therefore, measurement techniques often must be evaluated particularly for their ability to measure low concentrations with acceptable accuracy and precision. A methodology is presented here for determining objectively the lower (or upper) limit associated with a linear regression; that is, the point below (or above) which a regression model fails. Methods are also given for determining, provided the data include multiple observations at somexvalues, whether problems observed beyond the limit are due to increased variability or to breakdown of the linear relationship. The methodology is applied to calibration curve data from four chlorine measurement techniques, to estimate lower limits and to show that the principal problem found below the lower limit is dramatically increased variability.
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