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The effect of lithium on the electronic configuration of LixFeV3O8(0⩽x⩽2)

 

作者: M. Eibschu¨tz,   D. W. Murphy,   S. M. Zahurak,   P. A. Christian,  

 

期刊: Applied Physics Letters  （AIP Available online 1981）
卷期: Volume 39, issue 8  

页码: 664-666

 

ISSN:0003-6951

 

年代: 1981

 

DOI:10.1063/1.92812

 

出版商: AIP

 

数据来源: AIP

 

摘要:

The reduction of V ions in FeV3O8from V5+(3d0) and V4+(3d1) to V4+(3d1) and V3+(3d2) by lithiation withn‐BuLi has been inferred by57Fe Mo¨ssbauer effect. The Fe is localized and in the Fe3+state for allx.

 

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