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Approximate Theory of Viscosity and Thermal Conductivity in Dense Polyatomic Fluids

 

作者: Norman F. Sather,   John S. Dahler,  

 

期刊: Physics of Fluids(00319171)  (AIP Available online 1962)
卷期: Volume 5, issue 7  

页码: 754-768

 

ISSN:0031-9171

 

年代: 1962

 

DOI:10.1063/1.1724444

 

出版商: AIP

 

数据来源: AIP

 

摘要:

Formulas are derived for the collisional contributions to the pressure tensor and heat‐flux vector in fluids composed of molecules which interact with impulsive forces. An approximation scheme is then employed to obtain ``zero‐order'' estimates of the viscosity and thermal conductivity coefficients for various molecular models. The models considered are rough spherical and rigid convex molecular ``cores'' surrounded by potential staircases. The viscosity and thermal conductivity coefficients determined for the special case of cores surrounded by a square‐well attractive potential are found to vary approximately asT1/2eA/Tat ordinary liquid temperatures. Calculations are also presented of the variations of the transport coefficients with molecular shape and eccentricity parameters.

 

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