The role of association effects in a theory of an electrified interface
作者:
M.F. Holovko,
E.V. Vakarin,
期刊:
Molecular Physics
(Taylor Available online 1996)
卷期:
Volume 87,
issue 1
页码: 123-137
ISSN:0026-8976
年代: 1996
DOI:10.1080/00268979600100051
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
A theory for an electrode-associative ionic fluid interface is proposed. It takes into account the effect of interionic pairing as well as packing and electrostatics. The theory is based on the use of Wertheim's two-density formalism, i.e., the ions are represented as free and associated into dimers. Dimerization is made possible by the attractive interaction between sites embedded in each ion. The results for ionic density profiles calculated in a generalized exponential approximation are given. Analytical expressions for the differential capacitance, potential drop and adsorption coefficient calculated in the mean spherical approximation are presented.
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