Infrared studies of chain folding in polymers. VII. Amylose
作者:
J.L. Koenig,
P.D. Vasko,
期刊:
Journal of Macromolecular Science, Part B
(Taylor Available online 1970)
卷期:
Volume 4,
issue 2
页码: 347-367
ISSN:0022-2348
年代: 1970
DOI:10.1080/00222347008212507
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
Studies of chain folding in amylose employing spectroscopic techniques have led to an assignment of the 1295-cm−1band to a unique fold conformation. Irregular folds, present in single crystals, are regularized to the unique fold conformation during annealing. Annealing of solution-cast films, which initially contain a small amount of regular folding, increases the amount of regular folds. Swelling of these annealed films with water vapor destroys this unique folded conformation.
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