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Die Addition von Fluorcarbenen an Norbornadien: Eine Homo‐1,4‐addition

 

作者: Charles W. Jefford,   Ntanda Kabengele,   Josef Kovacs,   Ulrich Burger,  

 

期刊: Helvetica Chimica Acta  （WILEY Available online 1974）
卷期: Volume 57, issue 1  

页码: 104-113

 

ISSN:0018-019X

 

年代: 1974

 

DOI:10.1002/hlca.19740570110

 

出版商: WILEY‐VCH Verlag GmbH

 

数据来源: WILEY

 

摘要:

AbstractIt has been found that difluorocarbene undergoes extensive addition to theendo‐face of norbornadiene, yeilding the cheletropic adduct, 4.4‐difluorotetracyclo[3.3.0.02,8.03,6]‐octane. Similar behaviour has been observed for fluorochlorocarbene. Possible mechanisms to rationalize this novel behaviour of carbenes are disc

 

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