Polymerization of methylcyclooctadienes with ring opening
作者:
L.I.Red'kina,
K.L.Makovetskii,
I.L.Kershenbaum,
U.M.Dzhemilev,
G.A.Tolstikov,
期刊:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science
(Springer Available online 2004)
卷期:
Volume 30,
issue 1
页码: 112-115
ISSN:0568-5230
年代: 2004
DOI:10.1007/BF00962265
出版商: Springer_US-Boston
数据来源: Springer
摘要:
1.The polymerization of 1-methyl-1,5-cyclooctadiene using metathesis catalysts proceeds with opening of the ring exclusively at the unsubstituted double bond.2.We were the first to polymerize 3-methylcyclooctadiene and dimethyl-1,5-cyclooctadiene (mixture of 3,7- and 3,4-isomers) with opening of the ring to respectively give 1,4-polypiperylene and the alternating copolymer of piperylene with budadiene.3.The reaction of 1-methyl-1,5-cyclooctadiene with WCl6in the absence of cocatalysts leads to the formation of active centers, which are capable of initiating the polymerization of cycloolefins with opening of the ring.
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