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Polymerization of methylcyclooctadienes with ring opening

 

作者: L.I.Red'kina,   K.L.Makovetskii,   I.L.Kershenbaum,   U.M.Dzhemilev,   G.A.Tolstikov,  

 

期刊: Bulletin of the Academy of Sciences of the USSR, Division of chemical science  (Springer Available online 2004)
卷期: Volume 30, issue 1  

页码: 112-115

 

ISSN:0568-5230

 

年代: 2004

 

DOI:10.1007/BF00962265

 

出版商: Springer_US-Boston

 

数据来源: Springer

 

摘要:

1.The polymerization of 1-methyl-1,5-cyclooctadiene using metathesis catalysts proceeds with opening of the ring exclusively at the unsubstituted double bond.2.We were the first to polymerize 3-methylcyclooctadiene and dimethyl-1,5-cyclooctadiene (mixture of 3,7- and 3,4-isomers) with opening of the ring to respectively give 1,4-polypiperylene and the alternating copolymer of piperylene with budadiene.3.The reaction of 1-methyl-1,5-cyclooctadiene with WCl6in the absence of cocatalysts leads to the formation of active centers, which are capable of initiating the polymerization of cycloolefins with opening of the ring.

 

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