Morphology Transition from Sphere to Rod by Confining the Polymer Chains in a Dilute Microemulsion System
作者:
Kaori Nakaya,
Masayuki Imai,
Shigeyuki Komura,
Naohito Urakami,
期刊:
AIP Conference Proceedings
(AIP Available online 1904)
卷期:
Volume 708,
issue 1
页码: 106-107
ISSN:0094-243X
年代: 1904
DOI:10.1063/1.1764076
出版商: AIP
数据来源: AIP
摘要:
In this study we investigated the morphology transition of microemulsion droplet induced by polymer confinement using a small angle neutron scattering (SANS) technique. By confining the polymer chain strongly the scattering profiles showed the following changes; 1) a characteristic scattering peak corresponding to the size of droplet shifts to the higherqside, and 2) the scattering intensity in the lowqregion increases considerably. These changes of the scattering profiles can be described by a rod (or sphero‐cylinder) model. Thus, the strong confinement of polymer chains in droplets induces the morphological transition from spherical to rod‐like droplet. © 2004 American Institute of Physics
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