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Viscoelastic behavior of elastomers undergoing scission reactions

 

作者: J. Moacanin,   J.J. Aklonis,   R.F. Landel,  

 

期刊: Journal of Macromolecular Science, Part B  (Taylor Available online 1975)
卷期: Volume 11, issue 1  

页码: 41-55

 

ISSN:0022-2348

 

年代: 1975

 

DOI:10.1080/00222347508217854

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

A phenomenological prediction of the creep behavior of cross-linked polymers undergoing simultaneous physical relaxation and chemical network scission is presented. The fundamental assumption underlying this calculation is defined and its physical significance is discussed. The predicted response is related to the behavior of nonreacting polymers through a time-adjustment parameter. The magnitude and time dependence of this parameter depend on both the physical relaxation characteristics and the kinetics of the scission reaction. In the limit of totally elastic systems, a description of the well-known chemorheological behavior ensues.

 

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