Role of singlet oxygen in photo‐oxidative degradation and photostabilization of polymers
作者:
J. F. Rabek,
B. R̊anby,
期刊:
Polymer Engineering&Science
(WILEY Available online 1975)
卷期:
Volume 15,
issue 1
页码: 40-43
ISSN:0032-3888
年代: 1975
DOI:10.1002/pen.760150107
出版商: Society of Plastics Engineers, Inc.
数据来源: WILEY
摘要:
AbstractEvidence is presented that singlet oxygen may have an important role in the photo‐oxidation of polymers. Increased attention is being paid to singlet oxygen as a possible reactive intermediate in the initiation step of the photodegradation of polymers. Singlet oxygen may be produced by energy transfer either from impurities or internal groups after excitation, e.g. carbonyl groups, which are present in commercial polymers. As a consequence, reactions of singlet oxygen may also be important in the stabilization of polymers, e.g. leading to search for new and more effective antioxidant
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