Melt Viscosity Characteristics of Ethylene-Acrylic Acid-Acrylamide Terpofymer
作者:
B.H. Clampitt,
期刊:
Journal of Macromolecular Science: Part A - Chemistry
(Taylor Available online 1971)
卷期:
Volume 5,
issue 8
页码: 1317-1328
ISSN:0022-233X
年代: 1971
DOI:10.1080/00222337108061111
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
Melt index and melt viscosity measurements have been made on a series of ethylene-acrylic acid-acrylamide terpolymers. The terpolymers were prepared from a 2000 melt index ethylene-methyl acrylate copolymer and synthesis conditions were adjusted such that the polar groups varied from pure acid to pure amide to pure salt. Results of these measurements indicated the following order of melt viscosities at 190°C: 50% acid-50% amide < 100% amide < 100% acid < 33 1/3% acid amide-salt < 50% salt-50% amide < 50% salt-50% acid ≪ 100% salt. This order apparently arises because of the complex inter- and intramolecular hydrogen bonding and ionic bonding forces that exist in these systems.
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