A study of the electrochemical regeneration of phenol from sodium phenoxide solutions
作者:
David J. Pickett,
Ebrahim Akhavan‐Alizadeh,
期刊:
Journal of Applied Chemistry and Biotechnology
(WILEY Available online 1974)
卷期:
Volume 24,
issue 1‐2
页码: 63-70
ISSN:0375-9210
年代: 1974
DOI:10.1002/jctb.2720240108
出版商: John Wiley&Sons, Ltd
数据来源: WILEY
摘要:
AbstractAn experimental investigation has been made of the regeneration of phenol and caustic soda simultaneously by the electrolysis of aqueous sodium phenoxide in a cell using a cation exchange membrane as diaphragm. Current efficiencies close to 100% for both anodic and cathodic processes have been obtained for short periods of electrolysis but with prolonged operation considerable inefficiency arises due to adsorption and oxidation of phenol and loss of ion selectivity of the diaphragm. The presence of solid manganese dioxide in the electrolyte has been found to be useful in partially inhibiting the adsorption or oxidation of phenol at the anode.
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