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Oxidative Pretreathent with Hydrogen Peroxide Prior to Alkaline Pulping

 

作者: RobertV. Allison,   JosefS. Gratzl,  

 

期刊: Journal of Wood Chemistry and Technology  (Taylor Available online 1987)
卷期: Volume 7, issue 3  

页码: 285-309

 

ISSN:0277-3813

 

年代: 1987

 

DOI:10.1080/02773818708085269

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

Oxidative pretreatment of Southern pine wood with alkaline hydrogen peroxide increased its rate of delignification during subsequent kraft and soda-AQ pulping. Effective pretreatment required the removal of transition metals prior to oxidation at high pH (12), low teaperature (50°C) and short reaction time (<45 min.). Compared with reference pulping, pretreatment with 1.4% H2O2 and 3.3% NaOH on wood reduced pulping time to 35 kappa number by 30 minutes (at 170°C). Pre-oxidation resulted in pulp with yield-kappa number and viscosity-kappa number relations equal to or greater than those of corresponding reference pulp.

 

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