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Rapid Spectrophotometric Method for Determining Erythrosine, Amaranth and Tartrazine in Ternary Mixtures

 

作者: J.J. Berzas Nevado,   C. Guiberteau Cabanillas,   J. Rodriguez Flores,   A.M. Contento Salcedo,   M.J. Villaseñor LLerena,  

 

期刊: Analytical Letters  (Taylor Available online 1997)
卷期: Volume 30, issue 14  

页码: 2565-2578

 

ISSN:0003-2719

 

年代: 1997

 

DOI:10.1080/00032719708001766

 

出版商: Taylor & Francis Group

 

关键词: Spectrophotometry;zero-crossing measurement;simultaneous determination;erythrosine;amaranth;tartrazine

 

数据来源: Taylor

 

摘要:

A very simple spectrophotometric method using measurements at zero-crossing wavelength is described for resolving ternary mixtures of the food colorants Erythrosine (E-127), Amaranth (E-123) and Tartrazine (E-102). Calibration graphs are linear up to 14 mg/L of Erythrosine and 28 mg/L for Tartrazine and Amaranth. RSD of 0.80, 0.85 and 1.84% were obtained for nine standards of 8 mg/L of Erythrosine, 8 mg/L of Tartrazine and 8 mg/L of Amaranth, respectively. Detection limits of 0.052, 0.934 and 0.123 mg/L were obtained for Erythrosine, Tartrazine and Amaranth, respectively. This method was satisfactorily used for determining synthetic mixtures of these colorants in different ratios and it was successfully applied to a commercial product containing the three dyes; no separation step is required. The results were compared with those obtained by liquid chromatography and very similar values were found by both methods.

 

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