A New Analytical Solution of the Binary Copolymer Composition Equation and Suggested Procedure for Deriving the Monomer Reactivity Ratios
作者:
R.M. Joshi,
S.G. Joshi,
期刊:
Journal of Macromolecular Science: Part A - Chemistry
(Taylor Available online 1971)
卷期:
Volume 5,
issue 8
页码: 1329-1338
ISSN:0022-233X
年代: 1971
DOI:10.1080/00222337108061112
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
Anabsoluteanalytical procedure is found for obtaining the parameters of the differential, binary, copolymer composition equation, setting up a least-squares condition that places equal weight on all experimental lines of the Mayo-Lewis plot. The values of monomer reactivity ratios for the system ethyl methacrylate (M1-vinylidene chloride (M2), studied by Agron et al., are r1= 2.052 ± 0.043 and r2= 0.346 ± 0.052. These values, especially r1, differ from the estimates by Agron et al. The new solution, however, appears to yield the estimate of maximum likelihood for the reactivity ratios based on the given experimental data.
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