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A New Analytical Solution of the Binary Copolymer Composition Equation and Suggested Procedure for Deriving the Monomer Reactivity Ratios

 

作者: R.M. Joshi,   S.G. Joshi,  

 

期刊: Journal of Macromolecular Science: Part A - Chemistry  (Taylor Available online 1971)
卷期: Volume 5, issue 8  

页码: 1329-1338

 

ISSN:0022-233X

 

年代: 1971

 

DOI:10.1080/00222337108061112

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

Anabsoluteanalytical procedure is found for obtaining the parameters of the differential, binary, copolymer composition equation, setting up a least-squares condition that places equal weight on all experimental lines of the Mayo-Lewis plot. The values of monomer reactivity ratios for the system ethyl methacrylate (M1-vinylidene chloride (M2), studied by Agron et al., are r1= 2.052 ± 0.043 and r2= 0.346 ± 0.052. These values, especially r1, differ from the estimates by Agron et al. The new solution, however, appears to yield the estimate of maximum likelihood for the reactivity ratios based on the given experimental data.

 

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