The surface memory effect at conducting and dielectric surface coatings
作者:
LYUBOMIR V. TSONEV,
MINKO P. PETROV,
期刊:
Liquid Crystals
(Taylor Available online 1998)
卷期:
Volume 24,
issue 6
页码: 853-859
ISSN:0267-8292
年代: 1998
DOI:10.1080/026782998206678
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
The surface memory effect (SME) storage of smectic C textures in the nematic temperature range has been investigated at various conducting and dielectric orienting coatings. The surface memorization for p-n-heptyl-,-octyl- and-nonyl-oxybenzoic acids (HOBA, OOBA, NOBA) consisting of dimer molecules is relatively strong and is observed only on conducting coatings (ITO, SiO/ITO) while dielectric surfaces depress the effect. p-n-Decyloxybenzoic acid (DOBA) exhibits a SME neither for conducting nor for dielectric coatings. The basic role of adsorption in the surface memorization is discussed in combination with the influence of surface polarization and of certain mechanical properties of the liquid crystal molecules. It is demonstrated that the erasure activation energy V hyperbolically decreases with increasing cell thickness d and reaches saturation values at d 250mum. Probably this dependence indicates the role of the dielectric state of the coatings in the surface memorization process. The problem of the possible biaxial character of the memorized smectic C-like texture in the temperature range of the uniaxial nematic phase is also discussed.
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