Field-Induced Alignment of the Directors in the Smectic A Phase. Experiment and Simulation
作者:
GeoffreyRoger Luckhurst,
期刊:
Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals
(Taylor Available online 2000)
卷期:
Volume 347,
issue 1
页码: 121-135
ISSN:1058-725X
年代: 2000
DOI:10.1080/10587250008024834
出版商: Taylor & Francis Group
关键词: smectic A;director alignment;NMR;computer simulation
数据来源: Taylor
摘要:
In contrast to nematics far less is known about the alignment of the directors in a smectic A phase by an external field. To characterise this process, which necessarily involves the flow of the molecules, we have undertaken an NMR investigation of the smectic A phase of 4-octyl-4′-cyanobiphenyl. The results of these experiments have revealed that, as expected, the alignment of the directors is a complex process strongly influenced by the nature of the containing surface for the smectic A phase. To assist in understanding the alignment process we have used computer simulations to study the field induced alignment of the directors in the smectic A phase formed by the Gay-Berne mesogen GB(4.4,20.0,1,1).
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