Local polarity of latent ion tracks determined by solvatochromic molecular probes
作者:
M. Esser,
J. Fuhrmann,
期刊:
Radiation Effects and Defects in Solids
(Taylor Available online 1997)
卷期:
Volume 143,
issue 2
页码: 121-137
ISSN:1042-0150
年代: 1997
DOI:10.1080/10420159708212954
出版商: Taylor & Francis Group
关键词: Heavy ion tracks;Fluorescence;Dielectric constant;Poly(ethyleneterephthalate);Sensitization
数据来源: Taylor
摘要:
Fast heavy ions produce stable defects in most organic polymers. In this work poly(ethyleneterephthalate) was irradiated with Xe ions at an energy of about 11 MeV/u and an areal dose of about 2 × 1010cm−2. The tracks were characterized by soaking fluorescence tracers into the tracks using dimethylformamide as solvent. By analysing the band positions of solvatochromic dyes the local polarity can be obtained. A result of this characterization is that the dielectric number of the tracks is 10% decreased compared to the virgin polymer. By using the high polar solvent dimethylformamide as soaking agent it could be shown that there is no accomodation of this solvent in the tracks.
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