Multi-look polarimetric SAR (synthetic aperture radar) data can be represented either in Mueller matrix form or in complex covariance matrix form. The latter has a complex Wishart distribution. A maximum likelihood classifier to segment polarimetric SAR data according to terrain types has been developed based on the Wishart distribution. This algorithm can also be applied to multifrequency multi-look polarimetric SAR data, as well as 10 SAR data containing only intensity information. A procedure is then developed for unsupervised classification.