Odor of Monocyclic Partial Structures of Patchouli Alcohol and Related Compounds
作者:
Peter Weyerstahl,
Horst-Dieter Splittgerber,
Jörg Walteich,
Thomas Wollny,
期刊:
Journal of Essential Oil Research
(Taylor Available online 1989)
卷期:
Volume 1,
issue 1
页码: 1-8
ISSN:1041-2905
年代: 1989
DOI:10.1080/10412905.1989.9699437
出版商: Taylor & Francis Group
关键词: Substituted trimethylcyclohexanones;substituted trimethylcyclohexenols;substituted trimethylcyclohexanols;monocyclic patchouli alcohol partial structures;patchouli-like aromas.
数据来源: Taylor
摘要:
Numerous substituted trimethylcyclohexanones, trimethylcyclohexenols and trimethylhexanols have been synthesized from either 2,6,6-trimethylcyclohex-2-en-l-one or 3,5,5-trimethylcyclohex-2-en-l-one (isophorone). These compounds were examined as monocyclic partial structures of the tricyclic patchouli alcohol for their odor character and intensity. It was found that the size of the molecule (at least C10), substitution pattern, existence of a hindered tertiary hydroxyl group and the rigidity of structure were similarity determinants of the patchouli aroma character. Even so, the full balanced woody, earthy and camphoraceous character could not be found with any of them. Nevertheless, some of these simple monocyclic analogues possessed a lot of patchouli character. The odor intensity and quality for more than forty monocyclic compounds is described.
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