Desorption Potentials of Alkyl Alcohols and Specific Adsorption of Anions
作者:
A.Karim Shallal,
HenryH. Bauer,
期刊:
Analytical Letters
(Taylor Available online 1971)
卷期:
Volume 4,
issue 6
页码: 371-381
ISSN:0003-2719
年代: 1971
DOI:10.1080/00032717108058625
出版商: Taylor & Francis Group
关键词: specific adsorption of anions;tensammetry;alkyl alcohols;adsorption
数据来源: Taylor
摘要:
The potentials of desorption of various alkyl alcohols have been studied as a function of concentration of alcohol and of the nature and concentration of various electrolytes. Specific adsorption of the electrolyte ions is reflected in shifts of the desorption peaks of the alcohols. At anodic potentials, the order of specific adsorption appears to be chloride > sulfate >perchlorate > fluoride, and at cathodic potentials (vs. S. C. E.), chloride > perchlorate > sulfate > fluoride.
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