ABSTRACTIn situ water‐quality measurements, with respect to various ion and dissolved solids concentrations, have been closely approximated using open‐hole borehole geophysical logs. Analyses have shown good correlation between water resistivity (Rw, as determined from the logs) and dominant ion concentrations sampled from a wide range of water quality in Tertiary carbonate and granular formations.Rwcan be accurately determined by cross‐plotting saturated formation resistivity (Ro), obtained from normal or lateral resistivity logs, against formation bulk porosity from neutron, density, or acoustic velocity logs. Plotting these data on Hingle Resistivity‐Porosity Cross Plot (RPCP) paper with the proper matrix cementation factor (m, commonly 1.4 for unconsolidated sands or 1.6 for noncompacted Tertiary carbonates), will yield a graphical solution for Rwbased upon the relationship Rw=φmRo. The graphical technique also provides information concerning water‐quality variations with depth, true matric resistivity, location of confining beds, and vertical changes in formation porosity.Once Rwhas been determined, other ion concentrations can be estimated based upon chemical analyses of water samples from adjacent wells tapping a similar type water mass (i.e., calcium‐bicarbonate, sodium‐chloride water, etc.). Total dissolved solids (TDS), chloride, sulfate, potassium, sodium, magnesium, and hardness (as CaCO3) concentrations have consistently shown a high corre