Perturbation expansion of polymers in shear flow
作者:
Wilfried Carl,
期刊:
Macromolecular Theory and Simulations
(WILEY Available online 1995)
卷期:
Volume 4,
issue 1
页码: 77-86
ISSN:1022-1344
年代: 1995
DOI:10.1002/mats.1995.040040105
出版商: Hüthig&Wepf Verlag
数据来源: WILEY
摘要:
AbstractThe effect of shear flow on the excluded volume properties of bead spring chains is calculated via the perturbation expansion of the mean‐square end‐to‐end distance with respect to the excluded volume parameterz. The coefficient of the series 〈R2〉/〈R2〉0= 1 +C1·z− … vanishes for large flow rates but shows a strong dependence on the shear rate in the i
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