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C-Stannane derivatives of carbohydrates

 

作者: Laurance D. Hall,   Paul R. Steiner,   Diane C. Miller,  

 

期刊: Canadian Journal of Chemistry  （NRC Available online 1979）
卷期: Volume 57, issue 1  

页码: 38-43

 

ISSN:0008-4042

 

年代: 1979

 

DOI:10.1139/v79-006

 

出版商: NRC Research Press

 

数据来源: NRC

 

摘要:

Triphenyltin lithium (1) was reacted separately with 1,2:3,5-di-O-methylene-6-O-tosyl-α-D-glucofuranose (2), with methyl 2,3-anhydro-4,6-O-benzylidene-α-D-allopyranoside (4), and with methyl 2,3-anhydro-4,6-O-benzylidene-α-D-mannopyranoside (6), to form in each case a sugar-stannane derivative having a stable carbon-tin bond. These products have been studied by1H and13C nmr spectroscopy.

 

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