Carbon-13 and silicon-29 spin-lattice relaxation in phenylmethanes and phenylsilanes
作者:
RobinK. Harris,
RogerH. Newman,
期刊:
Molecular Physics
(Taylor Available online 1985)
卷期:
Volume 54,
issue 5
页码: 1021-1034
ISSN:0026-8976
年代: 1985
DOI:10.1080/00268978500100811
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
Carbon-13 and silicon-29 spin-lattice relaxation times and the corresponding nuclear Overhauser enhancements have been measured for PhnXH4-n(n= 1-4,X= C or Si). Thence dipolar and other contributions to the relaxation rate have been separated. The dipolar contribution is dominant, except for -CH3and -SiH3groups. Correlation times for overall molecular motion have been estimated, andT1ratios for phenyl groups have been used to compare the rotational mobility of the phenyl groups. Internal molecular motion is more hindered in phenylmethanes than in phenylsilanes. Results for diphenylmethane and diphenylsilane are consistent with strong coupling between internal and overall molecular motion.
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