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Synthesis of Novel Iron-Sulfur Complexes with Functional Ligands for Cluster Assembly

 

作者: Tomoyuki Mochida,   Mikio Ueda,   Hiroshi Moriyama,  

 

期刊: Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals  （Taylor Available online 2000）
卷期: Volume 342, issue 1  

页码: 91-96

 

ISSN:1058-725X

 

年代: 2000

 

DOI:10.1080/10587250008038250

 

出版商: Taylor & Francis Group

 

关键词: iron-sulfur cluster;ligand exchange reaction

 

数据来源: Taylor

 

摘要:

Iron-sulfur clusters containing a variety of ligands, [Fe4S4(SR)4]2-(R = 4-C6H4CHO, 4-C5H4N, 2-(4-NO2)C5H4N) were prepared as potential constituents for functional assembly. Preparation and structure of a mixed-cluster compound (Me4N)4[Fe(SPh)4] [Fe4S4(SPh)4], involving both rubredoxin and [4Fe-4S] ferredoxin model clusters, are also discussed.

 

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