Graphical Method for Polymerization Kinetics. II. Influence of Monomer Transfer on Molecular Weight Distribution for Anionic Polymerization Initiated by Multifunctional Initiator
作者:
De-Yue Yan,
期刊:
Journal of Macromolecular Science: Part A - Chemistry
(Taylor Available online 1986)
卷期:
Volume 23,
issue 1
页码: 129-147
ISSN:0022-233X
年代: 1986
DOI:10.1080/00222338608063381
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
This work deals with the kinetics of multifunctional polymerization with instantaneous initiation and monomer transfer. The set of very complicated kinetic differential equations is rigorously solved by a graphical method. Then, the expressions of the molecular weight distribution function, the number- and weight-average degree of polymerization, the distribution of functionality, the average functionality, etc. are obtained. Furthermore, a procedure is proposed for calculating the molecular weight distribution curve and the values of the other molecular parameters mentioned from the initial conditions of the polymerization.
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