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Graphical Method for Polymerization Kinetics. II. Influence of Monomer Transfer on Molecular Weight Distribution for Anionic Polymerization Initiated by Multifunctional Initiator

 

作者: De-Yue Yan,  

 

期刊: Journal of Macromolecular Science: Part A - Chemistry  (Taylor Available online 1986)
卷期: Volume 23, issue 1  

页码: 129-147

 

ISSN:0022-233X

 

年代: 1986

 

DOI:10.1080/00222338608063381

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

This work deals with the kinetics of multifunctional polymerization with instantaneous initiation and monomer transfer. The set of very complicated kinetic differential equations is rigorously solved by a graphical method. Then, the expressions of the molecular weight distribution function, the number- and weight-average degree of polymerization, the distribution of functionality, the average functionality, etc. are obtained. Furthermore, a procedure is proposed for calculating the molecular weight distribution curve and the values of the other molecular parameters mentioned from the initial conditions of the polymerization.

 

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