The pH in grapH
作者:
Robertde Levie,
期刊:
Critical Reviews in Analytical Chemistry
(Taylor Available online 1997)
卷期:
Volume 27,
issue 1
页码: 51-76
ISSN:1040-8347
年代: 1997
DOI:10.1080/10408349708050580
出版商: Taylor & Francis Group
关键词: pH calculations;stick diagrams;activity corrections
数据来源: Taylor
摘要:
We describe stick diagrams, which are simple graphs designed to provide quick insight into complicated ionic equilibria. Despite their inherent crudeness, they can be used to obtain numerical solutions to quantitative equilibrium problems. Moreover, they show when those quantitative answers are likely to be too approximate. Finally, we discuss how to make activity corrections, and conclude that activity corrections are often as large or larger than the errors involved in using stick diagrams. Therefore, in the absence of activity corrections, stick diagrams are usually quite adequate.
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