Quasiliving Carbocationic Polymerization. V. Quasiliving Polymerization of lndene
作者:
J. Puskás,
G. Kaszás,
J.P. Kennedy,
T. Kelen,
F. Tüdös,
期刊:
Journal of Macromolecular Science: Part A - Chemistry
(Taylor Available online 1982)
卷期:
Volume 18,
issue 9
页码: 1263-1274
ISSN:0022-233X
年代: 1982
DOI:10.1080/00222338208077222
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
Quasiliving polymerization of indene, i.e., an increase of the molecular weight of polyindenes with the cumulative amount of consumed monomer, has been demonstrated using the “H2O”/ BCl3, 2-chloroindene/BCl, “H2O”/TiCl4, 2-chloroindene/TiCl4, and cumyl chloride/TiCl4initiating systems in CH2Cl2solvent at -50°C. However, chain transfer operates in every system investigated, and sets a limit toDPn,max. The efficiency of the 2-chloroindene and cumyl chloride initiators is very low. The behavior of BCl3and TiCl4coinitiators on the polymerization has also been investigated.
点击下载:
PDF (450KB)
返 回