A new method for the determination of flow activation energy of polymer melt
作者:
D.R. Saini,
A.V. Shenoy,
期刊:
Journal of Macromolecular Science, Part B
(Taylor Available online 1983)
卷期:
Volume 22,
issue 3
页码: 437-449
ISSN:0022-2348
年代: 1983
DOI:10.1080/00222348308215200
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
A method based on the melt flow index rather than the conventional zero shear viscosity is suggested to estimate the activation energy for viscous flow of polymer melts. The method is particularly attractive due to its simplicity and because all the conditions for its derivation fit rather well within the validity range of applicability of the Arrheniustype equation relating viscosity and temperature. Values of activation energy for viscous flow using the suggested technique are calculated for a number of polymers falling within the olefinic, styrenic, cellulosic, and engineering thermoplastic groups.
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