Collision induced far infrared spectrum of liquid N2
作者:
D. Levesque,
J.J. Weis,
PH. Marteau,
J. Obriot,
F. Fondère,
期刊:
Molecular Physics
(Taylor Available online 1985)
卷期:
Volume 54,
issue 5
页码: 1161-1172
ISSN:0026-8976
年代: 1985
DOI:10.1080/00268978500100921
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
The collision induced far infrared spectrum of N2is evaluated by molecular dynamics using a model of quadrupole induced dipoles. The results for two high density, low temperature states (ϱ = 742 Amag,T= 81 K and ϱ = 610 Amag,T= 91 K) are compared with new measurements. The spectral line shapes show a faster decay at high frequency (v> 90 cm-1) than those given by experiment. The integrated absorption coefficient is shown to result from almost complete cancellation between two-, three-, and four-body contributions. The effect of the polarizability anisotropy on the integrated absorption and line shape is examined.
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