首页   按字顺浏览 期刊浏览 卷期浏览 Collision induced far infrared spectrum of liquid N2
Collision induced far infrared spectrum of liquid N2

 

作者: D. Levesque,   J.J. Weis,   PH. Marteau,   J. Obriot,   F. Fondère,  

 

期刊: Molecular Physics  (Taylor Available online 1985)
卷期: Volume 54, issue 5  

页码: 1161-1172

 

ISSN:0026-8976

 

年代: 1985

 

DOI:10.1080/00268978500100921

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

The collision induced far infrared spectrum of N2is evaluated by molecular dynamics using a model of quadrupole induced dipoles. The results for two high density, low temperature states (ϱ = 742 Amag,T= 81 K and ϱ = 610 Amag,T= 91 K) are compared with new measurements. The spectral line shapes show a faster decay at high frequency (v> 90 cm-1) than those given by experiment. The integrated absorption coefficient is shown to result from almost complete cancellation between two-, three-, and four-body contributions. The effect of the polarizability anisotropy on the integrated absorption and line shape is examined.

 

点击下载:  PDF (482KB)



返 回