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Hydrogen bonding in butadiene copolymers. II. Network relaxation

 

作者: E. P. Otocka,   F. R. Eirich,  

 

期刊: Journal of Polymer Science Part A‐2: Polymer Physics  (WILEY Available online 1968)
卷期: Volume 6, issue 5  

页码: 913-919

 

ISSN:0449-2978

 

年代: 1968

 

DOI:10.1002/pol.1968.160060510

 

出版商: John Wiley&Sons, Inc.

 

数据来源: WILEY

 

摘要:

AbstractThe mechanical lability of intermolecular hydrogen bonds in stoichiometric mixtures of acidic and basic butadiene copolymers has been studied by both infrared and mechanical methods. Comparison is made between the weight‐averagedE(t) andH(τ) spectra of the parent copolymers and those of the mixed copolymers. The results indicate that the maximum contributions of bond‐interchange relaxation migrate to shorter times as the concentration of bonding groups incre

 

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