Hydrogen bonding in butadiene copolymers. II. Network relaxation
作者:
E. P. Otocka,
F. R. Eirich,
期刊:
Journal of Polymer Science Part A‐2: Polymer Physics
(WILEY Available online 1968)
卷期:
Volume 6,
issue 5
页码: 913-919
ISSN:0449-2978
年代: 1968
DOI:10.1002/pol.1968.160060510
出版商: John Wiley&Sons, Inc.
数据来源: WILEY
摘要:
AbstractThe mechanical lability of intermolecular hydrogen bonds in stoichiometric mixtures of acidic and basic butadiene copolymers has been studied by both infrared and mechanical methods. Comparison is made between the weight‐averagedE(t) andH(τ) spectra of the parent copolymers and those of the mixed copolymers. The results indicate that the maximum contributions of bond‐interchange relaxation migrate to shorter times as the concentration of bonding groups incre
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