首页   按字顺浏览 期刊浏览 卷期浏览 Intercalation of Heavy Alkali Metals in Boron Substituted Carbons BxC1−x
Intercalation of Heavy Alkali Metals in Boron Substituted Carbons BxC1−x

 

作者: L. Duclaux,   B. Ottaviani,   L. Piraux,   E. Grivei,   J.P. Issi,   F. Beguin,   S. Flandrois,  

 

期刊: Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals  （Taylor Available online 1998）
卷期: Volume 310, issue 1  

页码: 27-32

 

ISSN:1058-725X

 

年代: 1998

 

DOI:10.1080/10587259808045310

 

出版商: Taylor & Francis Group

 

关键词: Boronated carbon;Heavy alkali metals;intercalation;X-ray diffraction;Electrical conductivity;Magnetoresistance;Interstratification.

 

数据来源: Taylor

 

摘要:

First stage intercalation compounds were obtained using vapor reaction of heavy alkali metals (M ˭ K, Rb and Cs) with BXC1−xplatelets (x=0.1 and x=0.25). Depending on the value of x, M(B0.1C0.9)8±1and M(B0.25C0.75)10±1compounds were formed. Intensity calculations of the001lines suggested domains of M(BXC1−x)5first stage dense structure. As formed B0.25C0.75was incompletely intercalated by cesium from its liquid ammonia solution whereas extended intercalation was obtained with heat treated B0.25C0.75host (T=1600°C) giving a first stage Cs(B0.25C0.75)12derivative.

 

点击下载:  PDF (271KB)



返 回