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Surface topography of phosphorus doped polysilicon

 

作者: Rama I. Hegde,   Wayne M. Paulson,   Philip J. Tobin,  

 

期刊: Journal of Vacuum Science&Technology B: Microelectronics and Nanometer Structures Processing, Measurement, and Phenomena  (AIP Available online 1995)
卷期: Volume 13, issue 4  

页码: 1434-1441

 

ISSN:1071-1023

 

年代: 1995

 

DOI:10.1116/1.588167

 

出版商: American Vacuum Society

 

关键词: THIN FILMS;SILICON;POLYCRYSTALS;PHOSPHORUS ADDITIONS;SURFACE STRUCTURE;ROUGHNESS;ATOMIC FORCE MICROSCOPY;GRAIN SIZE;Si:P

 

数据来源: AIP

 

摘要:

The surface topography of doped polysilicon films was investigated by atomic force microscopy for a wide range of doping and process conditions. These low‐pressure chemical vapor deposition silicon films were approximately 350 nm thick. The amorphous films wereinsituphosphorus doped during deposition at 550 °C, while the crystalline films were deposited at 625 °C and subsequently diffusion doped using either PH3or POCl3gases. Measured resistivities ranged from 700 to 10 000 μΩ cm corresponding to secondary ion mass spectrometry phosphorus concentrations that ranged from 8.45 to 0.95×1020cm−3.Insitudoped films exhibited the smoothest surface topography with a peak‐to‐valley surface roughness of 11 nm. The surface roughness values were 50 nm for PH3doped poly films, and as high as 135 nm for the POCl3doped films. Atomic force microscopy grain size analysis showed uniform distributions for theinsituand PH3doped films with grain sizes of 130 and 200 nm, respectively. POCl3doped poly‐Si showed bimodal grain size distributions, with the secondary grains measuring 500 nm in size and the normal grains averaging 225 nm. These secondary grains increased the surface roughness and their occurrence correlates with chlorine concentration. The number of secondary grains and their size increases with higher phosphorus content. Following the polyoxide growth, the surface roughness increased 3× to 5× with POCl3doping, but the surface topography increased only slightly for PH3andinsitudoped poly‐Si. After removing the polyoxide, the surface roughness decreased for the diffusion doped films.Insitudoped films retained their smooth surface following the oxidation and removal of the oxide.

 

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