Vibrational optical activity of anharmonic oscillator
作者:
P. L. POLAVARAPU,
期刊:
Molecular Physics
(Taylor Available online 1996)
卷期:
Volume 89,
issue 5
页码: 1503-1510
ISSN:0026-8976
年代: 1996
DOI:10.1080/002689796173309
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
Expressions for the vibrational optical activity of an independent anharmonic oscillator using the second-order contact transformation theory are presented. The relative importance of anharmonicity for the magnetic dipole and electric dipole transition moments is made transparent using the potential constants for Morse oscillator. At this level of theory, the anharmonic contributions appear to be relatively more significant for the magnetic dipole transition moments.
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