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Vibrational optical activity of anharmonic oscillator

 

作者: P. L. POLAVARAPU,  

 

期刊: Molecular Physics  (Taylor Available online 1996)
卷期: Volume 89, issue 5  

页码: 1503-1510

 

ISSN:0026-8976

 

年代: 1996

 

DOI:10.1080/002689796173309

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

Expressions for the vibrational optical activity of an independent anharmonic oscillator using the second-order contact transformation theory are presented. The relative importance of anharmonicity for the magnetic dipole and electric dipole transition moments is made transparent using the potential constants for Morse oscillator. At this level of theory, the anharmonic contributions appear to be relatively more significant for the magnetic dipole transition moments.

 

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