pH-Induced Difference Spectrophotometry in the Analysis of Binary Mixtures.
作者:
F. Salinas,
A. Espinosa-Mansilla,
A. Zamoro,
A.Muñoz de la Peña,
期刊:
Analytical Letters
(Taylor Available online 1996)
卷期:
Volume 29,
issue 14
页码: 2525-2540
ISSN:0003-2719
年代: 1996
DOI:10.1080/00032719608002789
出版商: Taylor & Francis Group
关键词: Difference spectrophotometry;binary mixtures analysis
数据来源: Taylor
摘要:
Difference spectrophotometry, based on the utilization of difference absorption spectra corresponding to the same compound obtained at two different pH's, has been investigated for the analysis of binary mixtures. The method has been applied to the simultaneous determination of bromophenol blue and methyl orange, and two different binary mixtures of sulfonamides i.e., sulfamethoxazole (SX)-sulfaquinoxaline (SQ) and sulfathiazole (ST)-sulfamethoxazole (SX). In addition, the determination of SX, SQ and ST in the presence of sulfanilamide (SB) has been performed. For the determination of ST and SX, first-derivative difference spectrophotometry was applied. A comparative study of the advantages of the pH-induced difference method with respect to first-derivative spectrophotometry is presented.
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