Macromolecular compounds
作者:
V.V.Korshak,
N.G.Matveeva,
期刊:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science
(Springer Available online 2005)
卷期:
Volume 2,
issue 2
页码: 313-318
ISSN:0568-5230
年代: 2005
DOI:10.1007/BF01171003
出版商: Springer_US-Boston
数据来源: Springer
摘要:
1.Polymerizability has been investigated in the halogen-substituted ethylene series, tetra- and di-haloethylenes being taken as examples.2.It has been established that steric hindrance to polymerization in the substituted-ethylene series is determined by the number and sizes of the substituents on the doubly bound carbon atoms.3.It has been found that the “limiting steric radius” for a substituent, is about 1.4–1.7 A in the case of tetra-substituted ethylenes.4.It has been shown that in the case of the asymmetrical dihaloethylenes polymerization is possible whatever the halogen may be.5.The polymerization of 1,1-dibromoethylene has been investigated.6.It has been shown that tetrabromo-, tetrachloro-, and tetratodoethylenes are not able to polym
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