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Macromolecular compounds

 

作者: V.V.Korshak,   N.G.Matveeva,  

 

期刊: Bulletin of the Academy of Sciences of the USSR, Division of chemical science  (Springer Available online 2005)
卷期: Volume 2, issue 2  

页码: 313-318

 

ISSN:0568-5230

 

年代: 2005

 

DOI:10.1007/BF01171003

 

出版商: Springer_US-Boston

 

数据来源: Springer

 

摘要:

1.Polymerizability has been investigated in the halogen-substituted ethylene series, tetra- and di-haloethylenes being taken as examples.2.It has been established that steric hindrance to polymerization in the substituted-ethylene series is determined by the number and sizes of the substituents on the doubly bound carbon atoms.3.It has been found that the “limiting steric radius” for a substituent, is about 1.4–1.7 A in the case of tetra-substituted ethylenes.4.It has been shown that in the case of the asymmetrical dihaloethylenes polymerization is possible whatever the halogen may be.5.The polymerization of 1,1-dibromoethylene has been investigated.6.It has been shown that tetrabromo-, tetrachloro-, and tetratodoethylenes are not able to polym

 

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