In this study, a transient thermal stress problem of a rectangular plate due to a nonuniform heat supply is treated theoretically and, thereafter, fracture behaviors of the plate with a crack are examined for compressive stress states. Assuming that a crack located on an arbitrary position, with an arbitrary direction, is sufficiently small and is closed because of the compressive stress field, a temperature field, in a transient state, is analyzed by taking into account the effect of relative heat transfer on both surfaces of the plate. Thereafter, the corresponding thermal stress analysis is developed on the basis of the two-dimensional plane stress problem using Airy's stress function method, and the stress intensity factor is analyzed for the biaxial stress state. As an analytical model, we consider mechanical boundary conditions of prescribed displacement and estimate the stress intensity factor of a crack tip using parameters of the crack configuration such as the location, direction, length, and coefficient of friction. These numerical results are shown in graphical form.